This is a first report in which the influence of the structure of polymeric binders, such as molecular weight (M), end-group functionality and cis-trans proportion, on the combustion behaviour of composite solid propellants (CSP) has been examined. In admixture with ammonium perchlorate (AP), dicarb
The effect of compositional variables upon oscillatory combustion of solid rocket propellants
โ Scribed by M.D. Horton; D.W. Rice
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- English
- Weight
- 526 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0010-2180
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โฆ Synopsis
In this test programme, a laboratory scale burner was used to study the oscillatory combustion o[ a composite propellant system. The results show that the variation o [ binders (polysulphide, polyurethane and polybutyl-acrylic acid) had a comparatively small effect upon the oscillatory combustion o[ the propellant system. Various burning rate modifiers (ammonium perchlorate particle size, copper chromite and lithium fluoride) greatly affected the oscillatory combustion o[ a polybutyl-acrylic acid propellant. Nomenclature * Velocity of sound in combustion gas E, The activation energy which describes gasification of the solid propellant [ Frequency of oscillations during growth period of oscillations ]a Frequency of oscillations during decay period j Exponent describing temperature sensitivity of burning rate (r=E,T 0 L Length of combustion gas column during growth or decay of oscillations m Exponent describing pressure sensitivity of burning rate (r=r0p") P Mean chamber pressure r Burning rate of solid propellant T~ Surface temperature of burning propellant V Flame velocity Y Real part of specific acoustic admittance of combustion zone % Exponential growth rate constant of oscillations e,~ 'Exponential' decay rate constant Amplitude of fractional perturbation in pressure at the combustion zone o-Amplitude of fractional perturbation in density accompanying 7 Ratio of specific heats of gas p Density of gas P~ Density of propellant
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