The effect of complexation on the rates of electron transfer of iron porphyrins
โ Scribed by L.A. Constant; D.G. Davis
- Book ID
- 108342890
- Publisher
- Elsevier Science
- Year
- 1976
- Weight
- 525 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0022-0728
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This review describes the relationship between the NMR chemical shifts and electronic structures of oneelectron oxidized products of iron(III) porphyrins such as iron(III) porphyrin radical cations or iron(IV) porphyrins. In the case of the former complexes, the iron(III) ions are classified into fo
Slow electron transfer to manganese(iii) porphyrins results when the macrocycle deviates from planarity. This was demonstrated by measuring the kinetics of homogeneous electron transfer from a series of semiquinone radical anions to synthetic manganese porphyrins (shown schematically; R =H, Cl, F; R