The effect of CO2in free-radical polymerization of 2,2,2-trifluoroethyl methacrylate
β Scribed by Soyoung Kwon; Won Bae; Hwayong Kim
- Book ID
- 110642016
- Publisher
- Springer US
- Year
- 2004
- Tongue
- English
- Weight
- 920 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0256-1115
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The free-radical polymerization of styrene has been studied in the homogeneous phase of supercritical (sc) CO 2 at 80 8C and pressures between 200 and 1 500 bar. 2,29-Azobisisobutyronitrile is used as initiator and CBr 4 as chain-transfer agent. The polymerization is monitored by means of online FT-
## Abstract We report first results on the controlled radical polymerization of 2,3βepithiopropyl methacrylate (ETMA) also known as thiiranβ2βylmethyl methacrylate. Reversible additionβfragmentation chain transfer (RAFT) of ETMA was carried out in bulk and in solution, using AIBN as initiator and t