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The effect of boric acid on the dehydration step in the formation of oxime from salicylaldehyde

✍ Scribed by Simionatto, Edesio L.; Yunes, Pablo R.; Yunes, Rosendo A.

Book ID
120073840
Publisher
Royal Society of Chemistry
Year
1993
Tongue
English
Weight
467 KB
Volume
7
Category
Article
ISSN
1472-779X

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πŸ“œ SIMILAR VOLUMES

Kinetics and mechanism for oxime formati
Kinetics and mechanism for oxime formation from benzoylformic acid: Electrostatic interactions in the dehydration of carbinolamines
✍ A. Malpica; M. Calzadilla; I. Mejias πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 140 KB

## Abstract The evidence establishes that oxime formation from benzoylformic acid in the pH range from 0.25 to 5.5 occurs with acid‐catalyzed dehydration of carbinolamines derived from the acid and its anion. The pH‐rate profile shows in order of decreasing pH in two regions: (1) In the pH range fr