✦ LIBER ✦

The effect of axial ligands on the reactivity and stability of the oxoferryl moiety in model complexes of Compound I of heme-dependent enzymes

✍ Scribed by Z. Gross

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 157 KB
Volume: 1
Category: Article
ISSN: 1432-1327
DOI: 10.1007/s007750050067

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Effects of a thiolate axial ligand on th

Effects of a thiolate axial ligand on the π→π* electronic states of oxoferryl porphyrins: a study of the optical and resonance Raman spectra of compounds I and II of chloroperoxidase

✍ Tsuyoshi Egawa; Denis A. Proshlyakov; Hideho Miki; Ryu Makino; Takashi Ogura; Te 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 144 KB

Effect of the thiazole moiety of thiamin

Effect of the thiazole moiety of thiamine hydrochloride and selected model compounds on cyanocobalamin stability

✍ Robert F. Doerge; Louis J. Ravin; Henry C. Caldwell 📂 Article 📅 1965 🏛 John Wiley and Sons 🌐 English ⚖ 370 KB 👁 2 views

Kinetics and mechanisms of substitution

Kinetics and mechanisms of substitution of the axial and equatorial ligands in an iron(II) macrocyclic heme model complex

✍ Henrique E. Tomam; Fabio S. Nunes 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 374 KB 👁 1 views

The complex [Fe(imox) (Nmim)~], where imox is a planar bis(iminooxime) macrocyclic ligand and Nmim = N-methyl imidazole, undergoes substitution reactions in the presence of 2,2'bipyridine (bipy), leading to a series of intermediate mixed complexes. The forward and reverse rate constants for the subs

Ligand-Modification Effects on the React

Ligand-Modification Effects on the Reactivity, Solubility, and Stability of Organometallic Tantalum Complexes in Water

✍ Dr. Ana Conde; Dr. Rosa Fandos; Dr. Carolina Hernández; Prof. Dr. Antonio Otero; 📂 Article 📅 2012 🏛 John Wiley and Sons 🌐 English ⚖ 450 KB 👁 1 views

Delocalization over the heme and the axi

Delocalization over the heme and the axial ligands of one of the two oxidizing equivalents stored above the ferric state in the peroxidase and catalase Compound-I intermediates: indirect participation of the proximal axial ligand of iron in the oxidation reactions catalyzed by heme-based peroxidases and catalases?

✍ R. Weiss; Dominique Mandon; Thomas Wolter; Alfred X. Trautwein; Markus Müther; E 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 243 KB

Effect of the axial cysteine ligand on t

Effect of the axial cysteine ligand on the electronic structure and reactivity of high-valent iron(IV) oxo-porphyrins (Compound I): A theoretical study

✍ Yoong-Kee Choe; Shigeru Nagase 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 454 KB 👁 1 views

## Abstract The effect of axial ligands on the reactivity of high‐valent iron(IV) oxo‐porphyrins (Compound I) was investigated using the B3LYP hybrid density functional method. We studied alkane hydroxylation using four models: Compound I with thiolate, imidazole, phenolate, and chloride anions as