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The effect of anchoring substitution on the course of a cation olefin bicyclization. Crystal structure of (±)-(2R, 3′R,5′S)-2-(3′-tert-Butyl-5-Isopropl-5′-Methyl-1′-Cyclopentenyl)-1-Cyclopentanone

✍ Scribed by Patrick Missiaen; Pierre J. De Clercq; Luc van Meervelt; Geoffrey S. D. King


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
536 KB
Volume
97
Category
Article
ISSN
0037-9646

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X-ray crystal structures of 1,2,4-tri-O-
✍ Thomas Richter; Peter Luger; Tadashi Hanaya; Hiroshi Yamamoto 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 780 KB

X-ray crystallographic analyses are reported for the two title compounds (8 and 9), of which the former crystallized in two modifications (8n and 8b). In all three structures, the pyranose rings have the %, (D) conformation and the substituents at C-l are axial and those at C-24-4 are equatorial. Th