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The effect of additives and solvents on the hydrogenolysis of 2-methyl-2-phenylaziridine derivatives with palladium catalyst

✍ Scribed by Sekio Mitsui; Yoshihiro Sugi

Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
227 KB
Volume
10
Category
Article
ISSN
0040-4039

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✦ Synopsis

In the previous paper (l), we reported the stereoselectivity of several Group VIII transition metal catalysts on the hydrogenolysis of 2-methyl-2-phenylaziridine and suggested that the configuration of the product is determined by the free energy difference of the transition states to form the carbon metal bond, which depends on the affinity of the catalyst for the nitrogen,

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