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The effect of added silver nitrate on the palladium-catalyzed arylation of allyltrimethylsilanes

โœ Scribed by Karabelas, Kostas; Westerlund, Christer; Hallberg, Anders

Book ID
120327421
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
646 KB
Volume
50
Category
Article
ISSN
0022-3263

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Palladium-catalysed arylation of vinyltr
Palladium-catalysed arylation of vinyltrimethylsilane in the presence of silver nitrate
โœ Kostas Karabelas; Anders Hallberg ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 127 KB

A series of aryZated vinyZtrimethyZsiZanes have been prepared by means of Heck Arytation in the presence of s'ilver nitrate, which serves to suppress the elimination 3f the silicon group and enhance the reaction rate. The importance of vinylsilanes as versatile precursors and their wide applications