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The E2Σ+ → C2Π Transition of NO and Term Values for the A, D, E, and C Lowest Rydberg Levels

✍ Scribed by V.D. Braun; K.P. Huber; M. Vervloet; C. Amiot; J. Vergès; K. Tsukiyama

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
311 KB
Volume
203
Category
Article
ISSN
0022-2852

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✦ Synopsis

The E 2 ⌺ ϩ 3 C 2 ⌸ Rydberg-Rydberg transition of 14 N 16 O near 8492 cm Ϫ1 has been studied by Fourier transform spectrometry in the emission from a dc excited supersonic jet expansion and from a dc discharge under equilibrium conditions. The same transition has also been observed in laser-induced stimulated emission. Line wavenumbers of the 0 -0, 1-1, and 2-2 bands, together with data for previously published near-infrared transitions, have been reduced to consistent sets of rovibronic term values for v ϭ 0, 1, and 2 of the A 2 ⌺ ϩ , D 2 ⌺ ϩ , E 2 ⌺ ϩ , and C 2 ⌸ states which frequently serve as intermediates in the multiphoton excitation of higher Rydberg levels of NO.

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