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The E1cB mechanism for thiocarbamate ester hydrolysis: equilibrium and kinetic studies

โœ Scribed by Bourne, Nicholas; Williams, Andrew; Douglas, Kenneth T.; Penkava, Thomas R.

Book ID
115311485
Publisher
Royal Society of Chemistry
Year
1984
Tongue
English
Weight
719 KB
Volume
11
Category
Article
ISSN
1472-779X

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We present results from ab initio and density functional theory studies of the mechanism for serine hydrolase catalyzed ester hydrolysis. A model system containing both the catalytic triad and the oxyanion hole was studied. The catalytic triad was represented by formate anion, imidazole, and methano