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The double hydrogen transfer in the 1-methoxy-2-propanol molecular ion: Loss of CH3CO by proton-transport catalysis

✍ Scribed by Karl J. Jobst; Nico M.M. Nibbering; Johan K. Terlouw

Book ID
113652617
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
551 KB
Volume
316-318
Category
Article
ISSN
1387-3806

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The spontaneous unimolecular dissociation reaction of methyl lactate (1) ionized by electron impact was investigated by a combination of mass-analyzed ion kinetic energy spectrometry and deuterium labeling. The metastable ions 1(+·) decompose in a variety of ways: four fragment peaks are observed at

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