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The Donnan equilibrium: I. On the thermodynamic foundation of the Donnan equation of state

✍ Scribed by Philipse, A; Vrij, A


Book ID
115460458
Publisher
Institute of Physics
Year
2011
Tongue
English
Weight
333 KB
Volume
23
Category
Article
ISSN
0953-8984

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Thermodynamics of the Laminar Donnan Sys
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Thermodynamic quantities of a polyelectroyte immersed in salt solution are derived modeling the polyelectrolyte by a sequence of charged parallel flat plates. The starting point for the analysis is the derivation of the Gibbs free enthalpy in its canonic variables pressure ( p) and temperature (T),