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The dissolution process of the NiO cathodes for molten carbonate fuel cells: state-of-the-art

✍ Scribed by S. Freni; F. Barone; M. Puglisi

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 302 KB
Volume: 22
Category: Article
ISSN: 0363-907X
DOI: 10.1002/(sici)1099-114x(199801)22:1<17::aid-er339>3.0.co;2-n

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✦ Synopsis

In this review article the analysis of the main problems related to the use of NiO as material for cathodes in Molten Carbonate Fuel Cells (MCFC) is reported. Thus, the most significant evidences of the mechanism of NiO dissolution have been reported as well as its correlation with the basicity of the carbonate melt, composition of the reactants gases and temperature. Some hypotheses described here have been also verified experimentally and the results of this validation are reported. In the final section, we have described the most promising alternative solutions to this problem and the advantages and shortcomings of these alternatives.

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