The dissociation-rate dependent electrochemical reduction of valinomycin complexes of monovalent ions

Formation and Dissociation of Tetrahedra

Formation and Dissociation of Tetrahedral Nickel(II) and Cobalt(II) Complexes of ‘Dithioimidodiphosphato’ Ligands, Measurement of Kinetically Determined Stability Constants, and Kinetic Investigations of the Rapid Formation of Tetrahedral Bis(ligand)copper(II) Complexes and Their Rates of Reduction to Trinuclear Copper(I) Species

✍ Peter Moore; William Errington; Satindra P. Sangha 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 German ⚖ 154 KB 👁 1 views

## Abstract The stopped‐flow technique was used to measure the rates of formation and dissociation of tetrahedral [ML~2~] complexes (M^2+^=Ni^2+^ or Co^2+^) of four bidentate S~2~‐donor ‘dithioimidodiphosphato’ ligands L^−^ (HL=[R^1^R^2^P(S)]NH[P(S)R^3^R^4^], R^1^ to R^4^=alkyl) at 25.0° in MeOH/