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The dispersion mechanism of TiB2 ceramic phase in molten aluminium and its alloys

✍ Scribed by A Jha; C Dometakis


Publisher
Elsevier Science
Year
1997
Weight
791 KB
Volume
18
Category
Article
ISSN
0261-3069

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✦ Synopsis


Titanium diboride TiB ceramic particulates are dispersed in molten aluminium and its alloys for grain 2 refining and for making cast metal1matrix composites. For producing cast MMC, the dispersion of the ceramic phase via in-situ aluminothermic reduction of K TiF and KBF flux mixture with molten 2 6 4 aluminium and, via the addition of exogenously formed TiB with the fluoride flux has been studied at 2 900ЊC. In this article, the aspects of interfacial energy that govern the dispersion and agglomeration of TiB particulates are examined. The Gibbs-adsorption interface equation is particularly employed to 2 define and to quantify the change in the surface energy as a function of the alloying element concentration and, consequently the effect of interfacial energy on the nucleation rate of TiB formed 2 via metallothermic reduction reaction and the size of the ceramic phase is also explained.


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