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The discharge of nitrate ions on platinum electrodes in the electrolysis of molten nitrates

✍ Scribed by W.E. Triaca; A.J. Arvía

Publisher
Elsevier Science
Year
1964
Tongue
English
Weight
151 KB
Volume
9
Category
Article
ISSN
0013-4686

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The anodic reaction occurring during the electrolysis of molten nitrates on graphite electrodes at temperature8 from 230 to 320°C has been studied. The overall reaction is 2N01-+ C = CO, + 2NOz + 2e. Current/voltage curves in the range 04-200 mA/cms fit a Tafel line with a slope ZRT/F. The decay of

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In the electrolysis of pure molten silver nitrate with a silver cathode and a platinum anode at temperatures from 220 to 380°C a reversible cell is formed. When the system is electrolysed for a short time at a steady current density and then the current is interrupted, it tends to reach after a few