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The direct synthesis of optically active trans-cyclooctene. Optically active trans-bicyclo[6.1.0]nonane

✍ Scribed by E.J. Corey; Joel I. Shulman

Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
209 KB
Volume
9
Category
Article
ISSN
0040-4039

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The optically active bicyclo[4.3.0]nonane derivative, considered to be the CD ring moiety of 12-oxygenated steroids was synthesized in the present study, which involved stereo-controlled formation of bicyclo[2.2.2]octane derivative by sequential Michael reaction, formation of tricyclo[5.2.2.0 2,6 ]u