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The direct synthesis of methylchlorosilanes: New aspects concerning its mechanism

โœ Scribed by Lars Lorey; Gerhard Roewer


Book ID
111611533
Publisher
Springer
Year
2002
Tongue
English
Weight
169 KB
Volume
1
Category
Article
ISSN
1569-0660

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A new enantiomerically pure P-chiral phosphine, (S)-cyclohexylmethyl- (1-naphthyl)phosphine (1) was prepared by phosphine-borane methodology and used in a mechanistic study of the Mitsunobu reaction. Enantiomerically enriched (S)-cyclo- hexylmethyl(1-naphtyl)phosphine oxide (8) is obtained if the re