The direct observation of 103Rh NMR
β Scribed by Devinder S Gill; Otto A Gansow; F.J Bennis; Kevin C Ott
- Publisher
- Elsevier Science
- Year
- 1979
- Weight
- 161 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0022-2364
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π SIMILAR VOLUMES
lo3Rh, 31P and 'H NMR data are reported for the cyclometallated Rh(II1) complexes of the type RhH(Y)(C-N)L,, where Y can be either an anionic or neutral ligand, C -N is a carbon-nitrogen bidentate ligand arising from cyclometallation at the imine carbon of the Schiffs bases derived from 2-amino-3-me
BARTOL RESEARCH FOUNDATTON NOTES 517 oxide (99.98 per cent pure) was irradiated by neutrons to produce Pr1h2 which was found to decay with emission of a single gamma ray at 1.6 Mev. NO gamma rays were detected in the disintegration of Pr143. Any present were estimated to have an intensity of upper
3): a) Metalation of (2) (1 g, 5.9 mol) in pentane (10 ml) with one equivalent of t-BuLi at 0 Β°C for 12 h furnishes a product, which, after removal of solvent, has the composition corresponding to (3a); dec. pt. 90 "C, soluble in ether, THF, dioxane.-b) Addition of TMEDA and of pentane to an etherea