𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The dipole moment of HOCl in vOH=4

✍ Scribed by Andrea Callegari; Patrice Theulé; Roman Schmied; Thomas R. Rizzo; J.S. Muenter

Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
129 KB
Volume
221
Category
Article
ISSN
0022-2852

No coin nor oath required. For personal study only.

✦ Synopsis

Pulsed laser excitation and photofragment detection methods are used to observe the 17 0;17 16 1;16 pure rotational transition within the v OH ¼ 4 vibrational state of HO 35 Cl. Microwave frequency and Stark effect measurements give m 0 ¼ 27484:33ð10Þ MHz and l b ¼ 1:562ð9Þ D. The dependence of l b , which is approximately parallel to the OH bond, on the level of OH stretch excitation appears linear and is consistent with that of H 2 O over the same 0-14 000 cm À1 energy range.

📜 SIMILAR VOLUMES

The dipole moment of CH335Cl
The dipole moment of CH335Cl
✍ G. Wlodarczak; B. Segard; J. Legrand; J. Demaison 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 170 KB
The dipole moment of HCN in the crystal
The dipole moment of HCN in the crystal
✍ D.G. Bounds; A. Hinchliffe; R.W. Munn; R.J. Newham 📂 Article 📅 1974 🏛 Elsevier Science 🌐 English ⚖ 309 KB

Ab initio molecular orbi'c31 &xl&ions on +Jc isolated HCN molecule in axial electric fields have been used in wn~unction with local fie!d theory to estimate that the effective dipole of ECN in its two crystalline forms is some 50% tiger than in the gas phase. i '.

The 4VOH Absorption Spectrum of HDO
The 4VOH Absorption Spectrum of HDO
✍ Olga Naumenko; Elena Bertseva; Alain Campargue 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 381 KB

The absorption spectrum of HDO was recorded by intracavity laser absorption spectroscopy in the 13 560 -14 050 cm Ϫ1 spectral region. Among 437 lines attributed to HDO, 399 were assigned to the 4 3 highly excited overtone transition. One hundred twenty-nine experimental energy levels were derived fr

The dipole moment of carbonyl oxides
The dipole moment of carbonyl oxides
✍ Richard W. Fessenden; J.C. Scaiano 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 386 KB

Carbonyl oxide generated by reaction or carben~ with oxygeq have been studied in time-resolved dielectric 10s~ experiments. The dipole moments of the oxides from benwphenone and dibenzosurberone are 4.0 and 3-B D. respectively.