✦ LIBER ✦
The dimesitylboron group in organic synthesis, IX. A most unusual reaction : Electrophilic attack on sulphur in α-thiocarbanions
✍ Scribed by Andrew Pelter; Gina Bugden; Ram Pardasani; John Wilson
- Book ID
- 104219205
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 191 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Predominant alkylation of a boron-stabilised carbanion containing an a-phenylthio group is unprecedentedly on sulphur rather than carbon. Even in lithium phenylthiomethane a similar effect can be observed, its importance being solvent dependant.