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The dimesitylboron group in organic synthesis 8. Preparations of 1,3-diols from oxiranes

โœ Scribed by Andrew Pelter; Gina Bugden; Richard Rosser

Book ID
104233304
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
222 KB
Volume
26
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Alkyldimesitylboranes, yield anions', by oxidation give 1,3-diols.

These anions

Mes2BCHR. that on reaction with oxiranes followed are thus the operational equivalent of RCHOH. The scope and limitations of the new process are delineated.

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