The dimerization of substituted 3-TMSO-1-alkynes with (φ3P)3RhCl

✍ Scribed by Thomas Rüping; Hellmut Singer

• Book ID: 104138393
• Publisher: Elsevier Science
• Year: 1987
• Tongue: English
• Weight: 283 KB
• Volume: 131
• Category: Article
• ISSN: 0020-1693
• DOI: 10.1016/s0020-1693(00)96031-6

✦ Synopsis

3-Trimethylsilyloxy-1

alkynes were prepared from 3-hydroxy-1 -alkynes and dimerized with (&P),RhCl as a catalyst. The influence of a steric effect on the rates of dimerization is demonstrated.