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The dimerization of 1,3-dienes with the nickel-ligand catalyst: evidence for a multi-step mechanism

✍ Scribed by B. Barnett; B. Büssemeier; P. Heimbach; P.W. Jolly; C. Krüger; I. Tkatchenko; G. Wilke


Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
164 KB
Volume
13
Category
Article
ISSN
0040-4039

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✍ G. Huybrechts; B. Van Mele 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB

Despite an extensive literature, controversy about the Diels-Alder reaction mechanism still exists. For the thermal dimerization of 1,3-butadiene, for example, a concerted one-step [I] or two-stage [2] mechanism, a mixture of orbital symmetry allowed and forbidden cycloadditions 131, as well as a tw