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The diffusion of hydrogen in disordered and ordered Pd3Mn as studied using the Gorsky relaxation

✍ Scribed by B. Sobha; B. Coluzzi; C. Costa; F.M. Mazzolai; T.B. Flanagan; Y. Sakamoto


Book ID
113182842
Publisher
Elsevier Science
Year
1991
Weight
562 KB
Volume
172-174
Category
Article
ISSN
0022-5088

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The hydroesterification of cyclohexene is catalyzed by a preformed Pd(PPh 3 ) 2 (TsO) 2 complex I in methanol as solvent. The effect of PPh 3 , TsOH, and water on the TOF has been evaluated. The system I/PPh 3 /TsOH = 1/6/8, in the presence of 800 ppm of H 2 O, at 373 K and under 2.0 MPa of CO leads