The deuteron quadrupole coupling constant in the deuteroxide ion

✍ Scribed by J.O. Clifford; M. Dixon; J.A.S. Smith

• Publisher: Elsevier Science
• Year: 1967
• Tongue: English
• Weight: 186 KB
• Volume: 1
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(67)85043-7

✦ Synopsis

The deuteron quadrupole coupling constant and asymmetry parameter of the OD-ion in LiOD -DzO are 267.7 kc/s and 0.044 at 273OK and 271.5 and 0.043 at 77O. compared to a theoretical estimate of 421.kc/s for the free ion from recent LCAO-MO-SCF wave-functions. We have recently observed deuteron magnetic resonance at 18.330 MC/S in a single crystal of LiOD -D20; the spectra were recorded