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The Deuterium Isotope Effect of Some Ionic Reactions of Benzaldehyde

โœ Scribed by Wiberg, Kenneth B.


Book ID
127136405
Publisher
American Chemical Society
Year
1954
Tongue
English
Weight
598 KB
Volume
76
Category
Article
ISSN
0002-7863

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Deuterium isotope effects on the zero-fi
โœ S.M. Neugebauer; D.S. Tinti ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 334 KB

The zero-field splitting parameters, D and E, in the lowest triplet state of pchlorobenzaldehyde, pmethylbenzaldehyde, and their d, isotopes (aldehyde proton), are determined by ODMR measurements. The results show that the sign of the isotopic change in D reflects the orbital character of the lowest