The determination of the homogeneous rate constant of the first order chemical reaction by a double step chronocoulometric method
β Scribed by Karel Holub
- Publisher
- Elsevier Science
- Year
- 1975
- Weight
- 345 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0022-0728
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π SIMILAR VOLUMES
## Abstract A method is proposed whereby the orders and rate constants for processes obeying the rate law β__dA__/__dt__ = __kA__^n^ may be determined. The method is illustrated in two ways. First, simulated data for processes of various orders are treated, and the treatment is shown to be capable
## Abstract A consecutive singleβroute reaction is considered. When two (groups of) steps compete in controlling the overall reaction rate, there exists a general rule that the earlier step in the flow of the overall reaction tends to be rateβdetermining with the increase of the reaction affinity.