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The Determination of the Geometry of Cu(II) Complexes: An EPR Spectroscopy Experiment

✍ Scribed by Garribba, Eugenio; Micera, Giovanni

Book ID
118272366
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
120 KB
Volume
83
Category
Article
ISSN
0021-9584

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Stabilities and Structures of Cu(II) Com
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## Abstract The pH‐dependent equilibria between Cu(II) and the potentially pentadentate ligands 4,7,10‐triazatridecane‐1,13‐diamine (__1__) and 1,9bis(2‐hydroxyphenyl)‐2,5,8‐triazanonane (**2**) have been studied in aq. solution at 298 K by EPR titration. Each ligand forms complexes CuLH~x~ (x=1,2,