The determination of rhodium and palladium using oscillographic polarography
β Scribed by W.H. Douglas; R.J. Magee
- Publisher
- Elsevier
- Year
- 1963
- Weight
- 730 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0368-1874
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π SIMILAR VOLUMES
The polarographic behaviour of oxygen gas dissolved in the molten binary KNO,-NaNO, mixture as well as that of its ionic species, OH-and OS-, has been studied by means of conventional and single sweep oscillographic polarography. A dme was used as cathode and an Ag/AgCl electrode was the reference;
An on-line microwave oven was employed in this study to accelerate the coordination reactions between Rh(III), Pd(II), and 2-(3,5-dicloro-2-pyridyl-azo)-5-dimethylaminoaniline (3,5-diCl-PADMA) in HOAc-NaOAc media. Two sensitive flow-injection spectrophotometric methods have been established for the