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The determination of kinetic data for the reactions of chromium(VI) with glutathione and other thiols

✍ Scribed by Joaquin F. Perez-Benito; Conchita Arias; Driss Lamrhari; Abdellah Anhari

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
276 KB
Volume
26
Category
Article
ISSN
0538-8066

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✦ Synopsis

The equations necessary for the determination of the rate constants corresponding to the opposite elementary steps for formation of the oxidant-reductant ester intermediate, as well as that corresponding to its redox decomposition, in the reduction of chromiumWI) by glutathione and other thiols at physiological pH have been deduced. It is shown that those three rate constants can be obtained with a good reproducibility.

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