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The determination of experimental signs of dipole moment derivatives: G sum rule analysis of allene

✍ Scribed by Mozart N. Ramos; A.B.M.S. Bassi; Roy E. Bruns


Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
151 KB
Volume
87
Category
Article
ISSN
0022-2852

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We show that the measurement of the absolute phase of the infrared-visible sum frequency susceptibility of a monolayer of molecules of lcnown orientation determines the relative sign of the dipole moment derivative and the polarizability derivative with respect to the normal mode. With the sign of t