The determination of chromium(III) and chromim(VI) by total anion exchange and atomic absortion spectrometry
β Scribed by M.S. Cresser; R. Hargitt
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 195 KB
- Volume
- 81
- Category
- Article
- ISSN
- 0003-2670
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β¦ Synopsis
The determination of chromium by atomic absorption spectrometry (a-a-s.) does not discriminate between the various oxidation states of the element. Recently, a method was required for the rapid dctcrmination of the concentrations of each of the two main oxidation states of chromium in soil cstracts, and this was achieved by combining total anion exchange with a.a.s.
Experiixen tal
AQQUratUS
An EEL 240 atomic absorption spectrophotomcter was used with ailacetylene and nitrous oxidcacetylsns burners. and a chromium hollowcathode lamp operated at 10 mA.
π SIMILAR VOLUMES
A simple method for the determination of chromium(III) and total chromium in a flow injection system comprising chelating ion-exchange and flame atomic absorption spectrometry (FAAS) was described. A minicolumn (85 mm x 1.6 mm i.d.) filled with a poly(aminophosphonic acid) chelating resin (PAPhA, 20
A seagomg method for the determmatlon of Cr(III) and total chrommm m sea water IS presented The method employs electron-capture detection of the volatile tnfluoroacetylacetone denvatlve of 0011) formed via solvent extra&on unth toluene, total chrommm IS determmed as Cr(III) after reduction DetectIon
In the flow system described, iron(I1) is measured spectrophotometrically with l,lO-phenanthroline, and total iron is determined in the same flow line by atomic absorption spectrometry. Linear calibration ranges are 0.1-35 and 0.1-10 rg ml-' for iron and total iron, respectively.