The method recently developed by our group for the determination of activity coefficients at infinite dilution by g.l.c., for systems involving moderately volatile solvents, is used in this work to determine the activity coefficients for the solutes: pentane, hexane, heptane, cyclopentane, cyclohexa
The determination of activity coefficients of alkanes, alkenes, cycloalkanes, and alkynes at infinite dilution with the polar solvents dimethyl sulphoxide (DMSO), orN,N-dimethylformamide (DMF), orN-methyl-2-pyrrolidinone (NMP) using a g.l.c. technique at the temperatures 283.15 K and 298.15 K
β Scribed by T.M. Letcher; P.G. Whitehead
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 135 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0021-9614
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β¦ Synopsis
This paper is a continuation of our investigation into the determination of activity coefficients Ε½ Ο± . at infinite dilution β₯ of hydrocarbons in polar solvents by medium pressure gas liquid 13 12 12
McGlashanαPotter equation.
π SIMILAR VOLUMES
This work is part of an investigation to determine activity coefficients at infinite dilution g a 13 of hydrocarbons in the industrially important polar solvent tetrahydrothiophene-1,1-dioxide (sulpholane), by medium pressure gas liquid chromatography (g.l.c.). In this work the activity coefficients
The present work is part of an investigation extending the determination of activity coefficients g a 13 at infinite dilution by medium-pressure g.l.c. to include volatile and polar solvents. The activity coefficient at infinite dilution for a series of n-alkane solutes (C5 to C7), cycloalkanes (C5