The determination and assignment of a complete 14N quadrupole coupling tensor in liquid solution
β Scribed by T.M. Plantenga; H. Bulsink; F.J.J. De Kanter; C. Maclean
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 414 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0301-0104
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Modulation cffccts induced by intcnction of an unpaucd clecuon wrth I4 N nuclc~ of pyrrolc rmgs in the electron spin echo from chlorophylIa radiui ntzons have been invcstigatcd. The moduhtmn frcqucncics have been detcrnrmed by Founer analysis of the echo sgnr11 decay. The modula~ioo frequencies appr
Using a self-consistent NMR method, it is now possible to determine both the deuterium quadrupole coupling constant as well as the rotational dynamic isotope effect in liquids. We successfully tested the method on benzene for temperatures between 280 K and 293 K. The average value of 185(3) kHz for