The design and synthesis of β-trifluoromethylenol phosphates as potential insecticides
✍ Scribed by Yixiang Ding; Xiaogen Huang
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 79 KB
- Volume
- 14
- Category
- Article
- ISSN
- 1042-7163
- DOI
- 10.1002/hc.10147
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
A new group of compounds, β‐trifluoromethylenol phosphates [(RO)~2~P(O)OCRCHCF~3~], has been designed and prepared by several methods. Some of them showed good insecticidal activities. In the molecular structure, the designed leaving group can rearrange to a powerful electrophilic agent, β,β‐difluorovinyl ketone, which would be a potential enzyme inhibitor. © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:304–308, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10147
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