Thermodynamics of the early stages in ho
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Roberto Fusco; Luca Longo
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Article
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1994
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John Wiley and Sons
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English
β 408 KB
## Abstract The ethylene polymerization enthalpy, calculated through quantumβmechanical abβinitio methods on model systems of homogeneous ZieglerβNatta cationic catalysts, is reported to be from two to three times greater than the experimental value of 22,3 kcal/mol. In this paper we analyze the or