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The decomposition of reinecke's salt, NH4[Cr(NH3)2(NCS)4]

✍ Scribed by J.E. House Jr.


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
231 KB
Volume
32
Category
Article
ISSN
0040-6031

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The formation of the title compounds by reaction of copper with yellow ammonium sulphide solutions is investigated. The new compound NIf,Cu,S, is isotypic to KCu,S, (space group P4/mmm, a = 3.907 A, c = 9.453 A) The topotactic decomposition of NI-I,Cu,S, to digenite between 120-140Β°C is studied and