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The decomposition of peroxynitrite to nitroxyl anion (NO-) and singlet oxygen in aqueous solution

✍ Scribed by Khan, A. U.; Kovacic, D.; Kolbanovskiy, A.; Desai, M.; Frenkel, K.; Geacintov, N. E.

Book ID
118122029
Publisher
National Academy of Sciences
Year
2000
Tongue
English
Weight
123 KB
Volume
97
Category
Article
ISSN
0027-8424

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Simple acidification o f aqueous alkaline peroxynitrite quantitatively generates singlet ('Ag) molecular oxygen, detected and quantitated spectroscopically (1 270 nm). This observation provides a chemical basis for physiological cytotoxicity o f ONOO-generated i n the diffusioncontrolled reaction o