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The Decomposition of Peroxycarbamates and their Efficiency as Initiators in Vinyl Polymerization 1,2

✍ Scribed by O'Brien, Eugene L.; Beringer, F. Marshall; Mesrobian, Robert B.


Book ID
125429277
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
524 KB
Volume
79
Category
Article
ISSN
0002-7863

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Formation of Group 4 Metallocene-Enolate
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The Group 4 metallocene bis(enolate) complexes [Cp 2 M(-O-CMeCH 2 ) 2 ] (1) add one or two molar equivalents of the organometallic Lewis acid B(C 6 F 5 ) 3 to form the addition products (3), respectively. Complexes 3 a (M Ti) and 3 b (M Zr) were characterized by X-ray diffraction. Complexes 2 under