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The decomposition of condensed phase fluorine azide

✍ Scribed by T.A. Seder; D.J. Benard

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
966 KB
Volume
85
Category
Article
ISSN
0010-2180

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✦ Synopsis

The burn rate of 5-80-t~m-thick cryogenic films of fluorine azide was determined by schlierern photography to be 1.6 + 0.2 mm/#s. This rate was found to be strongly influenced by the presence of N2F 2 , but less so by the presence of CO 2. By analogy with the results from the gas-phase decomposition of fluorine azide, the nascent decomposition products were expected to be NF(a) and N 2 . A thermal combustion mechanism driven by the energy released upon production and quenching of the NF(a) species was, therefore, proposed.

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