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The decomposition of 1-phenyl-3-chloro-nortricyclene and 1-phenylnortricyclene on reduction in 1,2-dimethoxyethane. The EPR spectra of the radical ions

✍ Scribed by Jorma Eloranta; Jaakko Paasivirta; Reijo Moilanen; Raili Vesterinen

Publisher: John Wiley and Sons
Year: 1972
Tongue: English
Weight: 316 KB
Volume: 4
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270040417

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✦ Synopsis

Abstract

Radical anions of 1‐phenyl‐3‐chloronortricyclene and 1‐phenylnortricyclene were produced by reduction with potassium in 1,2‐dimethoxyethane under a high vacuum. The initially formed radical anion of 1‐phenyl‐3‐chloronortricyclene was very unstable, and decomposed finally to the anions of naphthalene and biphenyl. The only product of the reduction of 1‐phenylnortricyclene was the biphenyl anion. The EPR spectra of the reaction mixtures were measured at temperatures from —80°C to room temperature.

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