Methyl radical reactions with matrix molecules in glasses C2H50H, (CH20H)z, n-and i-C3H70H, n-and i-C4HsOH, n-and i-CSHIlOH, C~DSOH, and i-C:+D70D, and the reactions of C:2H5, C3H7, C4H9, C : ~H I ~ with methanol glasses have been studied. Alkyl radicals were produced by photolysis of diphenylamine-
The decay kinetics of spin adducts formed by nitrosodurene with pentacarbonylrhenium(0) radical
β Scribed by Cheu Pyeng Cheng; H.S. Chen; Sen Ren Wang
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 520 KB
- Volume
- 359
- Category
- Article
- ISSN
- 0022-328X
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Although high-performance liquid chromatography with electrochemical detection (HPLC-EC) has been previously used to analyze radicals trapped by 5,5-dimethyl-1-pyrroline-N-oxide (DMPO), these techniques omitted the critical use of an internal standard. To improve reliability we have incorporated 3-c