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The Cα-Deprotonated Iminophosphorane Ph2P(CH2Py)(NSiMe3) as an N,N-Chelating Ligand for Iron and Zinc

✍ Scribed by Alexander Murso; Dietmar Stalke


Book ID
102170711
Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
165 KB
Volume
2004
Category
Article
ISSN
1434-1948

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✍ Stefan Wingerter; Heinz Gornitzka; Guy Bertrand; Dietmar Stalke 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 186 KB

Lithiation of triphenyl(trimethylsilylimino)phosphorane zinc complex [Zn(o-C 6 H 4 PPh 2 NSiMe 3 ) 2 ] (3). Reaction with CuCl 2 gives access to the new diiminophosphorane (o-Ph 3 P=NSiMe 3 with MeLi gives the ortho-metallated species [Li(o-C 6 H 4 PPh 2 NSiMe 3 )] 2 •Et 2 O (1), which exhibits all