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The Cycloaddition of Carbonyl-Flanked Methylene Bridges—A Novel Method for the Synthesis of Metallacycles

✍ Scribed by Christine Bauer; Ernst Guggolz; Prof. Dr. Wolfgang A. Herrmann; Gangolf Kriechbaum; Prof. Dr. Manfred L. Ziegler


Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
212 KB
Volume
21
Category
Article
ISSN
0044-8249

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**Surprising reactions of carbon monoxide with transition metal complexes** have been observed with compounds __(1)__ and __(2)__. The carbyne complex __(1)__ takes up CO at normal pressure and −30°C to form the metalated ketene __(2)__ which itself is deoxygenated by CO at +60°C and under 60atm pre