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The Curtius Rearrangement of Azidocarbonylfuroxans: Some Peculiarities and the Synthesis of Aminofuroxans

✍ Scribed by Igor V. Ovchinnikov; Alexander N. Blinnikov; Nina N. Makhova; Lenor I. Khmel’nitskii

Book ID
111729680
Publisher
Royal Society of Chemistry
Year
1995
Tongue
English
Weight
233 KB
Volume
5
Category
Article
ISSN
0959-9436

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Solid phase synthesis of aryl and hetero
Solid phase synthesis of aryl and heteroaryl amines using the Curtius rearrangement
✍ Satoshi Sunami; Takeshi Sagara; Mitsuru Ohkubo; Hajime Morishima 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 190 KB

An efficient method for the solid phase synthesis of secondary ary| amines and heteroaryl amines was developed. The key step was the formation of aryl or heteroaryl carbamates using the Curtius rearrangement of aryl carboxylic acids with Wang resin as a trapping hydroxyl group. N-alkylation reaction