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The cuprous chloride catalysed condensation of arsenious chloride with acetylene

✍ Scribed by Heweit, C. L. ;Jones, W. E. ;Vallender, H. W. ;Woodward, F. N.

Publisher
Wiley (John Wiley & Sons)
Year
1949
Weight
762 KB
Volume
68
Category
Article
ISSN
0368-4075

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✦ Synopsis

Abstract

Lewisite I, containing a small proportion of Lewisite II, is readily obtained in good yield by passing acetylene into a vigorously stirred mixture of arsenious chloride in carbon tetrachloride and a concentrated solution of cuprous chloride in aqueous ethanolamine hydrochloride. The reaction is most conveniently carried out continuously.

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