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The Crystal Structures of the Dicesium Dodecahalogeno-closo-Dodecaborates Cs2[B12X12] (X: Cl, Br, I) and Their Hydrates.

โœ Scribed by Ioannis Tiritiris; Thomas Schleid


Publisher
John Wiley and Sons
Year
2004
Weight
15 KB
Volume
35
Category
Article
ISSN
0931-7597

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Halogenation of nido-B 10 H 14 with C 2 H 2 Cl 4 , C 2 Cl 6 , Br 2 , or I 2 , produces by cluster degradation the (2 n)-closoclusters B 9 X 9 (X = Cl, Br, I). The synthesis of salts of the perhalogenated radical anions of the type (2 n + 1)-closo-[B 9 X 9 ] ยดยฑ and of the corresponding dianions (2 n