The Crystal Structure of α- and β-Cs2U2O7
✍ Scribed by F.C. Mijlhoff; D.J.W. Ijdo; E.H.P. Cordfunke
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 192 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0022-4596
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✦ Synopsis
The structure of anhydrous (\beta-\mathrm{Cs}{2} \mathrm{U}{2} \mathrm{O}{7}) has been redetermined. The compound is stabilized by water, and the structure of the stable compound in air, (\alpha-\mathrm{Cs}{2} \mathrm{U}{2} \mathrm{O}{7} \cdot 0.4 \mathrm{D}{2} \mathrm{O}), has been determined with neutron powder diffraction data. Infrared spectra show these (\mathrm{D}{2} \mathrm{O}) molecules to be chemically bonded. (1993
Academic Press. Inc.
📜 SIMILAR VOLUMES
Zn 28x Cu x )V 2 O 7 solid-solutions were synthesized by heating to 10003C, cooling to 7503C, and then quenching. Powder-di4raction patterns and the single-crystal structure re5nements of (Cu 0.56 Zn 1.44 )V 2 O 7 , (Cu 1.0 Zn 1.0 )V 2 O 7 , and (Cu 1.53 Zn 0.47 )V 2 O 7 show that the solid-solution
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