๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

The Crystal Structure of Zirconium(IV) Chloride: A New AB4-type Structure

โœ Scribed by Dr. B. Krebs

Publisher
John Wiley and Sons
Year
1969
Tongue
English
Weight
303 KB
Volume
8
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

โœฆ Synopsis

According to DTA measurements, compound ( I ) is stable up to a temperature of 371 "C in the absence of air. The electrical resistance I51 of the crystals increases linearly with temperature ~ as in metallic conductors. The compound is insoluble in dilute acids and alkalis; it decomposes in concentrated nitric and concentrated sulfuric acids. From single-crystal photographs it can be concluded that AuTezI crystallizes rhombically: a = 4.735, b -4.046, c = 12.55 A; Z = 2, dm = 8.00. dx = 7.98 g/cm3. Probable space groups Pmc21, Pma2, Pmma. The indexing of a powder diagram is given in Table 1. hkl d (A)

๐Ÿ“œ SIMILAR VOLUMES

The Crystal Structure of Ba2Cu2AlF11: a
The Crystal Structure of Ba2Cu2AlF11: a New Structure Type in Copper Fluoride Crystal Chemistry
โœ Nathalie Dupont; Ariel de Kozak; Patrick Gredin; Maurice Samouรซl ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 107 KB ๐Ÿ‘ 1 views

Ba 2 Cu 2 AlF 11 is trigonal: a = 7.301(1) A รŠ , c = 14.145(2) A รŠ , c = 120ยฐ, Z = 3. The crystal structure was solved in the space group P3 2 (nยฐ145), from X-ray single crystal data using 2675 unique reflections (2476 with F/r(F) > 4). It consists in a complex tridimensional arrangement of copperfl

The Crystal Structure of Ba2CuAlF9: a Ne
The Crystal Structure of Ba2CuAlF9: a New Structure Type in Copper Fluoride Chemistry
โœ Nathalie Dupont; Patrick Gredin; Stรฉphanie Fouquet; Ariel de Kozak ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 162 KB ๐Ÿ‘ 1 views

Ba 2 CuAlF 9 is monoclinic: a = 5.374(2) A รŠ , b = 7.312(2) A รŠ , c = 9.371(3) A รŠ , b = 90.20(1)ยฐ, Z = 2, space group P2 1 /c (nยฐ14). The crystal structure was solved from X-ray single crystal data using 1071 unique reflections (900 with F o /r(F o ) > 4, R factor = 0.075). It is built up from infi